Marvel movies aren’t exactly known for sweeping romantic moments, but there are a handful of iconic couples who manage to keep love alive while saving the world: Pepper Potts and Tony Stark, for example, or Vision and Wanda Maximoff.

The film and TV empire also boasts a few off-screen love matches too, though many of them happened before the Marvel Cinematic Universe was firmly established. Before Iron Man kicked off Phase 1 in 2008, there was 2003’s Daredevil, starring Ben Affleck as blind superhero Matt Murdock.

The movie wasn’t a critical hit, but it was the place where the Argo director fell in love with Jennifer Garner, who played Elektra. The former couple first met while filming 2000’s Pearl Harbor, but the Oscar winner later said that they didn’t really hit it off until 2002 when they were filming Daredevil.

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“That’s where I found my wife,” he told Playboy of the movie in 2013. The duo tied the knot in June 2005 and were married for 10 years before calling it quits. The twosome share three children: daughters Violet and Seraphina and son Samuel.

Keep scrolling for a look back at Marvel stars who once dated: