A Florida woman, described as unhinged after her divorce, was arrested following allegations that she shot and killed both of her former husbands in separate incidents on the same day, authorities reported.

On Wednesday, 48-year-old Susan Avalon was detained and charged with murder. She is accused of first shooting one ex-spouse in Tampa, then traveling over 50 miles to Manatee County to fatally shoot her other ex-husband around 3 p.m., shared Manatee County Sheriff Rick Wells.

Detectives have pointed to ongoing contentious custody disputes with her ex-husbands as a potential motive behind these shocking acts.

“This is as bold as it gets,” Wells stated during a press conference on Thursday.

“We believe this was a calculated act. She was aware of her intentions, had a plan in place, and came here with the purpose of killing her ex-husband,” he added.

Police said the alleged murderess targeted her first husband — a 54-year-old man she divorced roughly 11 years ago — at his Manatee County home around 2:55 p.m., luring him to open his front door with stolen food from a Panera Bread before shooting him twice.

The unidentified man was rushed to a nearby hospital, but succumbed to his injuries later that day.

Surveillance footage captured Avalon walking into the nearby bread eatery and swiping food from the delivery pickup shelf without paying before heading to her ex-husband’s home, authorities said.

Her live-in boyfriend allegedly told police she had recently tracked down her ex-hubby’s address.

The ex’s reportedly had ongoing custody disputes and about $4,000 in unpaid child support, with Avalon facing a looming deadline to pay $200 or lose her driver’s license.

Investigators tracked her silver Honda Odyssey back to her Citrus County home after the shooting and found her scrubbing the minivan with bleach and rags. But when asked by police about her ex-husband, she chillingly replied, “Which one?”

“We only know of one,” Wells said.

“We start to dig into this second ex-husband that we know nothing about, and we find she was married again after the marriage to our victim, and that this ex-husband lives in Tampa.”

Wells said investigators alerted Tampa authorities, who conducted a welfare check at the second husband’s Frierson Avenue home and found him dead inside with multiple gunshot wounds. The back door was also damaged, suggesting forced entry, he added.

Officials have not disclosed the second victim’s name or age, but believe Avalon allegedly killed him first.

The alleged killer, who was previously arrested on child abuse charges in Virginia in 2004, was charged with second-degree homicide in Manatee County. Wells said he is working with prosecutors to have that charge upgraded to first-degree murder and the death penalty.

Avalon, who reportedly has five children between both slain ex-husband’s, also faced two other child abuse cases in Tampa and Pasco County that were later dropped.

She has not yet been charged in the Tampa shooting as police continue their investigation.

Avalon is currently being held at Citrus County Detention Facility in Lecanto.